12X Grammy winner Alicia Keys appeared on 'It's on with Alexa Chung' to talk about winning awards, who she'd like to work with in the future, composing songs and that controversial performance with Jay-Z at the '2009 VMAs'.
R&B star Mario also appeared on the show to perform "Thinkin' About You" and "Break Up" with Sean Garrett, from his newly released album, D.N.A.
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